Av. Shevelkov et al., HELICAL 1(INFINITY(P(1)-) CHAINS IN THE STRUCTURES OF HG2P3BR AND HG2P3CL, Zeitschrift fur Kristallographie, 209(7), 1994, pp. 583-585
The crystal structures of Hg2P3Br (I) and Hg2P3Cl (II) have been refin
ed by least-squares full-matrix procedures to R = 0.037 (I) and R = 0.
035 (II). I is orthorhombic, space group Pbcn, a = 8.014(1) angstrom,
b = 8.902(1) angstrom, c = 7.823(1) angstrom, Z = 4. II is monoclinic,
space group C2/c, a = 7.834(2) angstrom, b = 8.844(1) angstrom, c = 7
.591(1) angstrom, beta = 98.68(1), Z = 4. Both structures consist of 1
infinity(P1-) helical chains running along the c-direction. The confor
mation of the chains is the same in I and II but the arrangement of th
e chains within the unit cells is different. The structures are also c
ompared with those of Cd2Z3X (X = Cl, Br, I; Z = P, As).