THE EFFECT OF ANODIC POLARIZATION ON THE AMBIENT CREEP OF BRASS

Citation
B. Gu et al., THE EFFECT OF ANODIC POLARIZATION ON THE AMBIENT CREEP OF BRASS, Corrosion science, 36(8), 1994, pp. 1437-1445
Citations number
15
Categorie Soggetti
Metallurgy & Mining
Journal title
ISSN journal
0010938X
Volume
36
Issue
8
Year of publication
1994
Pages
1437 - 1445
Database
ISI
SICI code
0010-938X(1994)36:8<1437:TEOAPO>2.0.ZU;2-9
Abstract
The effect of anodic and cathodic polarizations on the ambient creep o f brass in 3.5% NaCl and CH3COOH + CH3COONa solutions has been investi gated. The results showed that the creep rate in both solutions increa sed linearly with the increase of the anodic current density and was a pproximately inversely proportional to the square of the radius of the specimen. The depsilon/dt in 3.5% NaCl solution was much higher than that in the CH3COOH + CH3COONa solution at the same anodic current den sity. The creep rate resulting from dislocation climb induced by vacan cy supersaturation during the anodic polarization has been calculated as follows: depsilon/dt = K betai/r2 where K = 8pialphaMrhoD(s)DELTAtD ELTAr/C0dFZln (R/b), and beta is a constant related to the degree of d e-alloying. The experimental data support the proposed mechanism. Cath odic polarization could also increase the ambient creep of brass by a mechanism related to hydrogen-facilitated local plastic deformation.