KINETIC RESOLUTION OF ALIPHATIC OXIRANES MEDIATED BY IN-SITU FORMED MOLYBDENUM(VI) (OXO-DIPEROXO) HYDROXY ACID AMIDE CHIRAL DIOL COMPLEXES

Authors
SCHURIG V BETSCHINGER F
Citation
V. Schurig et F. Betschinger, KINETIC RESOLUTION OF ALIPHATIC OXIRANES MEDIATED BY IN-SITU FORMED MOLYBDENUM(VI) (OXO-DIPEROXO) HYDROXY ACID AMIDE CHIRAL DIOL COMPLEXES, Bulletin de la Societe chimique de France, 131(5), 1994, pp. 555-560
Citations number
15
Categorie Soggetti
Chemistry Inorganic & Nuclear",Biology,Chemistry
Journal title
Bulletin de la Societe chimique de France → ACNP
ISSN journal
00378968
Volume
131
Issue
5
Year of publication
1994
Pages
555 - 560
Database
ISI
SICI code
0037-8968(1994)131:5<555:KROAOM>2.0.ZU;2-R
Abstract
In situ-formed molybdenum(VI) (oxo-diperoxo) hydroxy acid amide/chiral diol complexes mediate the efficient kinetic resolution of simple ali phatic oxiranes. This method furnishes high enantiomeric yields of the residual oxirane. The oxidative cleavage of the oxiranes to carbonyl compounds is a non-stoichiometric reaction in the presence of oxygen.