Muon spin relaxation in zero field and longitudinal field was measured
in single crystal samples of KH2PO4 (KDP) and KD2PO4 (DKDP) over a te
mperature range of 5 K to 300 K. At low temperatures, diamagnetic muon
s and muon substituted radicals with nuclear hyperfine coupling can be
observed. For both KDP and DKDP, a minor change was observed in the d
ynamics of the muon below 140 K. Above 140 K, the mobility of the muon
appears to increase and the diffusion rate becomes faster with increa
sing temperature. Only a small increase in the relaxation rate is obse
rved in KDP due to the presence of the H+, suggesting that the relaxat
ion effects probably originate from the P-31.