A NEW SHORT SYNTHETIC APPROACH TO CYCLOPENTAPHENANTHRENONES

Citation
E. Gacsbaitz et al., A NEW SHORT SYNTHETIC APPROACH TO CYCLOPENTAPHENANTHRENONES, Tetrahedron, 50(34), 1994, pp. 10359-10366
Citations number
41
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
ISSN journal
00404020
Volume
50
Issue
34
Year of publication
1994
Pages
10359 - 10366
Database
ISI
SICI code
0040-4020(1994)50:34<10359:ANSSAT>2.0.ZU;2-3
Abstract
The Diels-Alder reactions of 4-acetoxy-2-cyclopenten-1-one and 2-bromo -4-acetoxy-2-cyclopenten-1-one with vinylarenes are discussed. The aro matization of the reaction product opens a new two- step route for the synthesis of cyclopentaphenanthrenones. Structure analysis of reactio n products by H-1 and C-13-NMR spectroscopy is reported.