The objective of this work was to produce grout-treated soils with per
meability coefficients less than 10(-7) cm/sec that would be suitable
as containment barriers around hazardous waste landfills. The role of
such admixtures as superplasticizers and silica fume in grouts for mix
ing with soil was investigated. Grouts were designed to be used with s
oil-mixing or jet-grouting techniques for in situ installation of barr
iers. Materials with a range of soil-cement ratios were tested for per
meability and strength under wet and simulated subsurface curing condi
tions. Permeability coefficients of the order of 10(-10) cm/sec were m
easured for soil cements with soil-cement ratios by mass up to 5, depe
nding on how the materials were cured. The use of superplasticizers in
parent grouts to reduce water-cement ratio decreases permeability up
to four orders of magnitude compared to soil cements produced from con
ventional high water-cement ratio grouts. The significant improvement
in performance results in reduced thickness of barriers for hydraulic
and physical isolation of contaminants, and hence greater cost effecti
veness.