We report the far-infrared photoconductivity spectroscopy (FIRPCS) of
the high purity n-GaAs grown by molecular beam epitaxial (MBE) techniq
ue. The current-voltage (I-V) measurement and FIRPCS under different e
lectric field strength have been performed on high purity n-GaAs at 4.
2 K. Except for photothermal ionization process, a new far-infrared ph
otoconductivity (FIRPC) mechanism is observed. This photo ionization p
rocess is assisted by impact ionization and depends on external electr
ic field. This new mechanism originates from photo-field ionization.