Aspects of the chemistry, photochemistry, and photophysics of solid-st
ate host-guest assemblies (SSHGA) are reviewed. Materials such as cycl
odextrins, inclusion clathrates, and zeolites can be used to encapsula
te a variety of organic guests. The resulting SSHGA can exhibit photop
hysical properties which are significantly different from those of the
unincluded guest. Examples are drawn from emission spectroscopic, pho
tochemical, and nonlinear optical properties of the host-guest assembl
ies.