Cx. Lu et G. Odian, CATIONIC RING-OPENING POLYMERIZATION OF BICYCLIC AMIDE ACETALS, Journal of polymer science. Part A, Polymer chemistry, 32(12), 1994, pp. 2283-2290
Various bicyclic amide acetals were synthesized from the cycloaddition
reactions of 2-substituted-2-oxazolines with styrene oxide. Ring-open
ing polymerization of the bicyclic amide acetals occurred upon heating
in the presence of methyl tosylate. Characterization of the bicyclic
amide acetals and their polymers was accomplished by NMR and elemental
analysis. Vapor pressure osmometry showed the highest polymer molecul
ar weight was only 2,400. The mechanisms for cycloaddition and polymer
ization are discussed. (C) 1994 John Wiley & Sons, Inc.