SYNTHESIS AND X-RAY STRUCTURAL CHARACTERIZATION OF THE 1-1 ADDUCT OF BISMUTH(III) WITH THE SALTREN ANION [SALTREN-EQUIVALENT-TO-N(CH2CH2N=CHC6H4OH)3] - A NOVEL 7-COORDINATE BISMUTH(III) COMPLEX

Authors
BHARADWAJ PK LEE AM MANDAL S SKELTON BW WHITE AH
Citation
Pk. Bharadwaj et al., SYNTHESIS AND X-RAY STRUCTURAL CHARACTERIZATION OF THE 1-1 ADDUCT OF BISMUTH(III) WITH THE SALTREN ANION [SALTREN-EQUIVALENT-TO-N(CH2CH2N=CHC6H4OH)3] - A NOVEL 7-COORDINATE BISMUTH(III) COMPLEX, Australian Journal of Chemistry, 47(9), 1994, pp. 1799-1803
Citations number
8
Categorie Soggetti
Chemistry
Journal title
Australian Journal of Chemistry → ACNP
ISSN journal
00049425
Volume
47
Issue
9
Year of publication
1994
Pages
1799 - 1803
Database
ISI
SICI code
0004-9425(1994)47:9<1799:SAXSCO>2.0.ZU;2-S
Abstract
The synthesis and single-crystal X-ray structure determination of the title compound are recorded; crystals are monoclinic, P2(1)/c, a 10.30 9(8), b 18.817(7), c 15.542(6) angstrom, beta 121.80(5)-degrees-, Z 4; R was 0.038 for 2894 independent, 'observed' [I > 3delta(I)] reflecti ons. The molecule has quasi-3 symmetry, with seven-coordinate bismuth [Bi-N(apical), 2.82(1); Bi-N, 2.512(8)-2.563(9); Bi-O, 2.197(8)-2.300( 8) angstrom].