A SYNTHETIC ROUTE TO EPOXYALKYL BETA-LAMINARIBIOSIDES, ESPECIALLY SUITABLE FOR RADIOLABELING

Authors
BEST WM STICK RV TILBROOK DMG
Citation
Wm. Best et al., A SYNTHETIC ROUTE TO EPOXYALKYL BETA-LAMINARIBIOSIDES, ESPECIALLY SUITABLE FOR RADIOLABELING, Australian Journal of Chemistry, 47(9), 1994, pp. 1805-1809
Citations number
2
Categorie Soggetti
Chemistry
Journal title
Australian Journal of Chemistry → ACNP
ISSN journal
00049425
Volume
47
Issue
9
Year of publication
1994
Pages
1805 - 1809
Database
ISI
SICI code
0004-9425(1994)47:9<1805:ASRTEB>2.0.ZU;2-P
Abstract
The major products in the controlled benzylation (NaH/PhCH2Cl) of ally l and but-3-enyl beta-D-glucopyranosides were the 2,4,6-tri-O-benzyl e thers. Subsequent glycosidations of these tribenzyl ethers gave deriva tives of allyl and but-3-enyl beta-laminaribioside, the latter being s ubsequently transformed into 3,4-epoxybutyl beta-laminaribioside.