DENSITIES, REFRACTIVE-INDEXES, SPEEDS OF SOUND AND SHEAR VISCOSITIES OF DIETHYLENE GLYCOL DIMETHYL ETHER-METHYL SALICYLATE AT TEMPERATURES FROM 298.15 TO 318.15-K
Tm. Aminabhavi et al., DENSITIES, REFRACTIVE-INDEXES, SPEEDS OF SOUND AND SHEAR VISCOSITIES OF DIETHYLENE GLYCOL DIMETHYL ETHER-METHYL SALICYLATE AT TEMPERATURES FROM 298.15 TO 318.15-K, Collection of Czechoslovak Chemical Communications, 59(7), 1994, pp. 1511-1524
Densities, refractive indices, speeds of sound and viscosities of the
diethylene glycol dimethyl ether-methyl Salicylate system were measure
d as a function of mole fraction at 298.15, 303.15, 308.15, 313.15 and
318.15 K. The results are fitted by a power series equation involving
both the temperature and mole fraction variables. The basic physical
data of the mixtures are further used to calculate the excess molar vo
lume V(E), changes in isentropic compressibility DELTAbeta, changes in
refractivity DELTAR and changes in viscosity DELTAeta. The results ar
e fitted by the Redlich-Kister polynomial relation. The isobaric therm
al expansion coefficients of the mixtures are also determined from den
sity measurements. The data are compared with those obtained from equa
tions derived by differentiation of the Lorentz-Lorenz and Eykman rela
tions. Refractive indices of the mixture are used to test the validity
of mixing relations. The changes in isobaric thermal expansion coeffi
cients DELTAalpha of the mixtures were examined. Viscosity data were t
ested in terms of the McAllister, Heric and Auslaender relations.