CATALYTIC HYDROSILYLATION OF CARBON-MONOXIDE WITH COBALT CARBONYLS

Authors
SISAK A MARKO L ANGYALOSY Z UNGVARY F
Citation
A. Sisak et al., CATALYTIC HYDROSILYLATION OF CARBON-MONOXIDE WITH COBALT CARBONYLS, Inorganica Chimica Acta, 222(1-2), 1994, pp. 131-134
Citations number
28
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Inorganica Chimica Acta → ACNP
ISSN journal
00201693
Volume
222
Issue
1-2
Year of publication
1994
Pages
131 - 134
Database
ISI
SICI code
0020-1693(1994)222:1-2<131:CHOCWC>2.0.ZU;2-S
Abstract
The hydrosilylation of carbon monoxide with cobalt carbonyls under rel atively mild conditions resulted in a Fischer-Tropsch-analogous reduct ive coupling of CO. Alkyl silyl ethers, 1,2-bis(silyloxy)-1-alkenes an d higher molecular weight compounds with at least three silyloxy group s were also formed, each of these containing up to seven carbon atoms derived from CO and for the most part having a linear structure. A (si lyloxycarbyne)cobalt complex was postulated as the key intermediate.