NONLINEAR-OPTICAL MATERIALS CONTAINING MOLYBDENUM OR TUNGSTEN MONONITROSYL REDOX CENTERS - 2ND-HARMONIC GENERATION BY HETEROBIMETALLIC COMPLEXES CONTAINING FERROCENYL DONOR AND MOLYBDENUM MONONITROSYL ACCEPTORGROUPS SEPARATED BY AN ARYL RING

Authors
COE BJ JONES CJ MCCLEVERTY JA BLOOR D KOLINSKY PV JONES RJ
Citation
Bj. Coe et al., NONLINEAR-OPTICAL MATERIALS CONTAINING MOLYBDENUM OR TUNGSTEN MONONITROSYL REDOX CENTERS - 2ND-HARMONIC GENERATION BY HETEROBIMETALLIC COMPLEXES CONTAINING FERROCENYL DONOR AND MOLYBDENUM MONONITROSYL ACCEPTORGROUPS SEPARATED BY AN ARYL RING, Polyhedron, 13(14), 1994, pp. 2107-2115
Citations number
50
Categorie Soggetti
Chemistry Inorganic & Nuclear",Crystallography
Journal title
Polyhedron → ACNP
ISSN journal
02775387
Volume
13
Issue
14
Year of publication
1994
Pages
2107 - 2115
Database
ISI
SICI code
0277-5387(1994)13:14<2107:NMCMOT>2.0.ZU;2-R
Abstract
The compounds (NO){HB(3,5-Me2pz)3}X{EC6H3-(3-R)-{4-(eta5-C5H4)Fe (eta5 -C5H5)}] (M = Mo, E = NH, R = H, Me, X = Cl, I; M = Mo, E = O, R = H, X = Cl, I; M = W, E = NH, R = H, Me, X = Cl, M = W, E = 0, R = H, X = Cl) and (3,5-Me2pz)3}{OC6H4-4-{(eta5-C5H4)Fe(eta5-C5H5)}2] (M = Mo, W) have been synthesised and their second order non-linear optical prope rties assessed using the Kurtz powder test; 3,5-Me2pz)3}I{NHC6H4-4-{(e ta5-C5H4)Fe(eta5-C5H5)}] gave a signal of similar intensity to that of a urea standard but the others gave weak or undetectable signals.