THE TEMPLATE SYNTHESIS AND CHARACTERIZATION OF ALKALINE-EARTH METAL-ION NITRATE MACROACYCLIC SCHIFF-BASE COMPLEXES

Authors
RADECKAPARYZEK W PATRONIAK V
Citation
W. Radeckaparyzek et V. Patroniak, THE TEMPLATE SYNTHESIS AND CHARACTERIZATION OF ALKALINE-EARTH METAL-ION NITRATE MACROACYCLIC SCHIFF-BASE COMPLEXES, Polyhedron, 13(14), 1994, pp. 2125-2128
Citations number
26
Categorie Soggetti
Chemistry Inorganic & Nuclear",Crystallography
Journal title
Polyhedron → ACNP
ISSN journal
02775387
Volume
13
Issue
14
Year of publication
1994
Pages
2125 - 2128
Database
ISI
SICI code
0277-5387(1994)13:14<2125:TTSACO>2.0.ZU;2-6
Abstract
The template reaction of 2,6-diacetylpyridine with 1,8-diaminonaphthal ene in the presence of calcium(II), strontium(II) and barium(II) nitra tes produced the new hexadentate N4O2 open-chain complexes as a result of [2 + 1] Schiff base condensation, irrespective of the molar ratio of starting materials used in the synthesis. They were characterized b y IR, UV-vis, H-1 NMR and analytical data. No [2 + 2] macrocyclic comp lexes were isolated, either in the template synthesis, nor on the trea tment of the [2 + 1] acyclic complexes with diamine.