SYNTHESIS OF AZINES, AZOLES AND FUSED AZOLES FROM ALPHA-ARYLHYDRAZONONITRILE

Citation
Ie. Islam et Sm. Elamin, SYNTHESIS OF AZINES, AZOLES AND FUSED AZOLES FROM ALPHA-ARYLHYDRAZONONITRILE, Revue Roumaine de Chimie, 39(5), 1994, pp. 577-581
Citations number
5
Categorie Soggetti
Chemistry
Journal title
ISSN journal
00353930
Volume
39
Issue
5
Year of publication
1994
Pages
577 - 581
Database
ISI
SICI code
0035-3930(1994)39:5<577:SOAAAF>2.0.ZU;2-G
Abstract
The reaction of alpha-arylhydrazononitrile 1 with hydrazine hydrate, p henylhydrazine, mercaptoacetic acid, ethylene diamine, o-phenylene-dia mine, o-aminothiophenol and o-aminophenol is described to give the cor responding pyrazolthioles 3, 4 and the corresponding azoles 5, 6, 7, 8 and 9, respectively. Also compound 1 reacts with malononitrile, ethyl cyanoacetate and phenylisothiocyanate to give the corresponding azines , 10, 11 and 12, respectively.