Ie. Islam et Sm. Elamin, SYNTHESIS OF AZINES, AZOLES AND FUSED AZOLES FROM ALPHA-ARYLHYDRAZONONITRILE, Revue Roumaine de Chimie, 39(5), 1994, pp. 577-581
The reaction of alpha-arylhydrazononitrile 1 with hydrazine hydrate, p
henylhydrazine, mercaptoacetic acid, ethylene diamine, o-phenylene-dia
mine, o-aminothiophenol and o-aminophenol is described to give the cor
responding pyrazolthioles 3, 4 and the corresponding azoles 5, 6, 7, 8
and 9, respectively. Also compound 1 reacts with malononitrile, ethyl
cyanoacetate and phenylisothiocyanate to give the corresponding azines
, 10, 11 and 12, respectively.