Rg. Iococca et Dj. Duquette, THE EFFECT OF OXYGEN PARTIAL-PRESSURE ON THE OXIDATION BEHAVIOR OF CARBON-FIBERS AND CARBON-FIBER GLASS MATRIX COMPOSITES, Journal of Materials Science, 29(16), 1994, pp. 4294-4299
Carbon fibres were examined for oxidative stability, both in the as-re
ceived condition and in a carbon fibre/glass matrix composite, to dete
rmine the effect of oxygen partial pressure on their oxidation behavio
ur. The oxidation data as a function of oxygen partial pressure (0.05,
0.21, and 1.0 atm) were then analysed to determine how the structure
of the fibre surface impacts the oxidation behaviour. For the as-recei
ved material, it was determined that the data are best described by Te
mkin-type adsorption kinetics, while the fibres encased in the glass m
atrix exhibited Langmuir-type kinetics. This relevance of this distinc
tion is discussed.