Y. Huai et al., STUDY OF DENSITY IN PULSED-LASER DEPOSITED AMORPHOUS-CARBON FILMS USING X-RAY REFLECTIVITY, Applied physics letters, 65(7), 1994, pp. 830-832
We report the accurate determination of the absolute density of the pu
lsed-laser deposited amorphous carbon ultrathin films as well as the f
ilm density evolution with the substrate temperatures T(s) (22-300-deg
rees-C) using high-resolution x-ray reflectivity. The density values r
ho for the films deposited with laser power density of 8 X 10(8) W/cm2
varied from 3.10 to 2.40 g/cm3 as the substrate temperature increased
from 22 to 300-degrees-C. This result, together with the optical band
-gap values obtained by transmittance measurements, clearly indicates
a diamond-like to graphite-like microstructure change near T(s) = 200-
degrees-C.