The electronic structure, binding energy, and correlation functions of
three different spatial configurations of D- centers in GaAs-based se
miconductor structures are studied using a numerical technique that so
lves the two-electron Schrodinger equation for such systems. We compar
e our results for the quantum well D-w(-) with experimental data and v
ariational and diffusion Monte Carlo calculations: We demonstrate the
existence of the spatially separated D-s(-) center as a bound state, e
ven in the regime of very low magnetic fields, and find interesting an
ticrossings among the energy levels in its electronic structure, which
underlie a spectrum composition df a D-0 donor center and a free elec
tron in a magnetic field. For the remote D-r(-) center we find that st
rong electron-electron correlations can give rise to magnetic-field-in
duced angular-momentum transitions, and as the magnetic held increases
, these correlations weaken, while eventually the system magnetically
evaporates approaching the classical unbound regime.