Atomic hydrogen interaction with the Si(111)4 x 1-In surface phase was
studied using low-energy electron diffraction, Anger electron spectro
scopy, and scanning tunneling microscopy. Upon hydrogen action mostly
Si-ln outer bonds are broken and are replaced by Si-H, and In is freed
to form islands without Si movement. It was found that the underlying
atomic layer of a substrate of the Si(111)4 x 1-In surfacephase has a
reconstruction with the same periodicity as the In layer. A structura
l model of this substrate reconstruction is proposed, based on the rec
ently proposed extended Pandey chain model for the Si(111)3 x 1 Ag- an
d alkali-metals-induced substrate reconstruction.