IS THE LOCAL-DENSITY APPROXIMATION EXACT FOR SHORT-WAVELENGTH FLUCTUATIONS

Citation
K. Burke et al., IS THE LOCAL-DENSITY APPROXIMATION EXACT FOR SHORT-WAVELENGTH FLUCTUATIONS, Physical review letters, 73(9), 1994, pp. 1283-1286
Citations number
28
Categorie Soggetti
Physics
Journal title
ISSN journal
00319007
Volume
73
Issue
9
Year of publication
1994
Pages
1283 - 1286
Database
ISI
SICI code
0031-9007(1994)73:9<1283:ITLAEF>2.0.ZU;2-N
Abstract
A commonly cited reason for the success of the local spin density (LSD ) approximation is that it correctly accounts for short wavelength con tributions to the exchange-correlation energy. We show that this resul t, while true in several limits and for several approximations to thes e fluctuations, is not exact in general, with an analytic demonstratio n on a specific system (Hooke's atom). Nevertheless, we find that LSD is rather accurate for small separations.