Roughly 3000 rearrangement pathways have been calculated for each of t
wo clusters bound by simple empirical potentials. The first system is
the 55-atom complex described by a pairwise Lennard-Jones potential. T
he second consists of 55 C-60 molecules with an intermolecular potenti
al obtained by spherically averaging atom-atom Lennard-Jones terms, as
previously employed in bulk simulations. Various properties of the pa
thways are calculated, such as a cooperativity index and the integrate
d path length, and the probability distributions are subjected to stat
istical analysis. Systematic differences between the atomic Lennard-Jo
nes clusters and the C-60 molecular clusters are explained in terms of
the effective pair potential; e.g., rearrangements of (C-60)(5)5 are
generally localized because the potential is relatively short ranged.
A pseudo-third-derivative correction is developed to improve the conve
rgence of the eigenvector-following method employed to optimize the ge
ometries and follow the pathways.