CRITICAL NEUTRON-SCATTERING IN A POLYMER BLEND ABOVE AND BELOW THE CRITICAL-POINT OF DEMIXING - CRITICAL EXPONENTS AND AMPLITUDE RATIOS

Citation
D. Schwahn et al., CRITICAL NEUTRON-SCATTERING IN A POLYMER BLEND ABOVE AND BELOW THE CRITICAL-POINT OF DEMIXING - CRITICAL EXPONENTS AND AMPLITUDE RATIOS, Physical review letters, 73(10), 1994, pp. 1452-1455
Citations number
22
Categorie Soggetti
Physics
Journal title
ISSN journal
00319007
Volume
73
Issue
10
Year of publication
1994
Pages
1452 - 1455
Database
ISI
SICI code
0031-9007(1994)73:10<1452:CNIAPB>2.0.ZU;2-Y
Abstract
The critical behavior of a polymer blend was measured by small-angle n eutron scattering above and below the critical temperature T-c, i.e., outside and inside the unstable region. The critical exponents and the amplitudes of the susceptibility and the correlation length were dete rmined. For T > T-c the critical exponents gamma and nu are consistent with the renormalization-group predictions. Below T-c, however, devia tions from the expected values were observed. Also experimental critic al amplitude ratios (20-30)% smaller than predicted were found.