D. Muller et al., THE SHOSHONITE PORPHYRY CU-AU ASSOCIATION IN THE GOONUMBLA DISTRICT, NSW, AUSTRALIA, Mineralogy and petrology, 51(2-4), 1994, pp. 299-321
The Goonumbla porphyry copper-gold deposit in N.S.W., Australia, is ho
sted by late Ordovician (439.2 +/- 1.2 Ma) shoshonitic igneous rocks.
In terms of their petrography, the rocks vary from andesitic to daciti
c lavas and tuffs which are partly intruded by monzonite stocks; they
are characterized by high and variable Al2O3 (13.4-19.9 wt%), very hig
h K2O values (up to 6.8 wt%) and high K2O/Na2O ratios (0.58-1.48), whi
ch are typical for the shoshonite association. The rocks also have enr
iched LILE concentrations (Ba up to 1200 ppm, Sr up to 1350 ppm), low
HFSE (TiO2, < 0.67 wt%, Zr < 125 ppm, Nb < 10 ppm, Hf < 3.4 ppm), and
very low LREE (La < 22.4 ppm, Ce < 31 ppm), which are typical for pota
ssic volcanic rocks formed in a late oceanic-are setting. Mineral chem
istry of selected magmatic mica and apatite phenocrysts from host rock
s reveals relatively high SrO and BaO contents (micas: similar to 0.15
wt% and up to 0.28 wt%, respectively; apatites: up to 0.28 wt% and 0.
19 wt%, respectively) and very high halogen concentrations. Micas are
characterized by up to 3.9 wt% F and 0.14 wt% Cl, whereas apatites hav
e up to 3.6 wt% F and 0.68 wt% Cl These very high halogen contents com
pared to those from barren intrusions imply that the shoshonitic magma
tism was the source of mineralization. Copper-gold mineralization cons
ists mainly of bornite, chalcopyrite, chalcocite and minor pyrite and
tetrahedrite. Native gold occurs mainly as minute grains within silica
tes of the host rocks, and more rarely as fine inclusions in the sulph
ides. Mineralization is accompanied by wallrock alteration comprising
a spatially restricted potassic type and a regional propylitic alterat
ion type.Thus, the porphyry copper-gold deposit in the Goonumbla distr
ict can be viewed as an additional example of a worldwide association
between potassic/shoshonitic magmatism and base- and precious-metal mi
neralization. More specifically, it appears to be the oldest recorded
example of a shoshonite-associated porphyry Cu-Au deposit from a late
oceanic-are setting, a possible modern analogue being Ladolam at Lihir
Island, Papua New Guinea.