We report on the structural and optical properties of GaN epitaxial la
yers grown on 6H-SiC. We employed the sublimation sandwich method to g
row single crystal layers at high growth rates with free carrier conce
ntrations of 2 x 10(17) cm-3. Very narrow x-ray diffraction peaks of t
he GaN (0002) plane are obtained indicating the high quality of this s
ystem. These findings are directly reflected in the optical properties
. The photoluminescence shows a single sharp exciton line with a half
width of 4 meV. Impurity related donor acceptor transitions are seen w
ith very weak intensities. However, at lower energies the internal lum
inescence transitions of the 3d transition metal ions Fe and V are obs
erved.