N. Merchant et al., REACTION INDUCED TEXTURE OF (BI,PB)2SR2CA2CU3O10+DELTA AG COMPOSITE CONDUCTORS/, Applied physics letters, 65(8), 1994, pp. 1039-1041
A considerable body of evidence collected on silver-sheathed (Bi,Pb)2S
r2Ca2Cu3O10+delta (Bi-2223/Ag) composite conductors heat treated witho
ut any additional rolling or pressing (beyond fabrication of the initi
al composite) has revealed that significant texturing of the Bi-2223 g
rains occurs as the Bi-2223 formation reaction takes place. During hea
t treatment, Bi-2223 is produced via a reaction between Bi-2212 and se
cond phases in the core of the composite. As the Bi-2223 forms, it dev
elops texture by what appears to be a grain growth mechanism. These co
ncurrent processes ultimately result in a well-textured, single-phase
conductor even when no additional rolling or pressing is done to the i
nitial composite. This observation raises important questions about th
e relative contributions of the heat treatment and deformation steps t
o texture development during conventional oxide-powder-in-tube process
ing of Bi-2223/Ag composite conductors.