Aa. Kernoghan et al., RESONANCES ABOVE THE IONIZATION THRESHOLD IN POSITRON HYDROGEN SCATTERING, Journal of physics. B, Atomic molecular and optical physics, 27(16), 1994, pp. 120000543-120000549
Resonances appearing above the ionization threshold in coupled-state c
alculations of positron-atom scattering are discussed. Calculations in
the six-state approximation Ps(1s,2s,2p) + H(1s,2s,2p), which show su
ch resonance structure, are compared with a more extensive 18-state ap
proximation Ps(1s, 2s, 3sBAR, 4sBAR, 2p, 3pBAR, 4pBAR, 3dBAR, 4dBAR) (H (1s, 2s, 3sBAR, 4sBAR, 2p, 3pBAR, 4pBAR, 3dBAR, 4dBAR) in which ch
annels other than 1s, 2s and 2p are represented by pseudostates. The r
esults strongly indicate that the above ionization threshold resonance
s observed in the six-state approximation, and in other small basis se
t calculations, are not real. It is suggested that they are a conseque
nce of the neglect, or inadequate representation in other approximatio
ns, of ionization channels. In the six-state approximation the positro
nium component of the system wavefunction attempts to represent the mi
ssing ionization channels but in so doing produces unreal resonances a
bove the ionization threshold. More generally, it is suggested that, i
n coupled-state calculations of positron-atom scattering, the atom par
t of the system wavefunction will try to compensate for defects in the
positronium component and vice versa. When the defects are serious, f
or example, the omission of important ionization channels, unusual spu
rious behaviour is to be expected.