OXIDATION OF ALKANES CATALYZED BY BINUCLEAR METAL-COMPLEXES - CONTROLBY THE COORDINATION SPHERE

Authors
VINCENT JM MENAGE S LAMBEAUX C FONTECAVE M
Citation
Jm. Vincent et al., OXIDATION OF ALKANES CATALYZED BY BINUCLEAR METAL-COMPLEXES - CONTROLBY THE COORDINATION SPHERE, Tetrahedron letters, 35(34), 1994, pp. 6287-6290
Citations number
16
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron letters → ACNP
ISSN journal
00404039
Volume
35
Issue
34
Year of publication
1994
Pages
6287 - 6290
Database
ISI
SICI code
0040-4039(1994)35:34<6287:OOACBB>2.0.ZU;2-A
Abstract
The oxidation of cyclohexane by t-butyl hydroperoxide is catalyzed by binuclear ore-bridged non heme iron complexes.?he effects of varying t he coordination sphere of iron on catalytic activity are studied point ing to the overall charge of the complex being a key factor. An active dimanganese complex is found to be much more robust than the correspo nding iron complex.