NITRILE ADDITION TO TRICARBONYLCYCLOHEXADIENYLIUM COMPLEXES - THE EFFECT OF PERCHLORATE COUNTERANION

Authors
ONG CW CHAO YK CHANG YA
Citation
Cw. Ong et al., NITRILE ADDITION TO TRICARBONYLCYCLOHEXADIENYLIUM COMPLEXES - THE EFFECT OF PERCHLORATE COUNTERANION, Tetrahedron letters, 35(34), 1994, pp. 6303-6304
Citations number
6
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron letters → ACNP
ISSN journal
00404039
Volume
35
Issue
34
Year of publication
1994
Pages
6303 - 6304
Database
ISI
SICI code
0040-4039(1994)35:34<6303:NATTC->2.0.ZU;2-8
Abstract
A method for the preparation of the tricarbonylcylohexadienyliumiron p erchlorate salt and their reactions with TMS-CN were investigated. The nucleophilic addition reactions of TMS-CN were insensitive to the per chlorate counteranion since it cannot dissociate into a nucleophlilic species to release the free cyanide anion. A reductive workup was deve loped to avoid decompositions.