BEHAVIOR OF 2-SUBSTITUTED AND 2,6-DISUBSTITUTED BENZOYLOXYL RADICALS - ELECTRONIC AND STERIC EFFECTS OF THE SUBSTITUENTS

Authors
WANG J TSUCHIYA M SAKURAGI H TOKUMARU K ITOH H
Citation
J. Wang et al., BEHAVIOR OF 2-SUBSTITUTED AND 2,6-DISUBSTITUTED BENZOYLOXYL RADICALS - ELECTRONIC AND STERIC EFFECTS OF THE SUBSTITUENTS, Tetrahedron letters, 35(34), 1994, pp. 6321-6324
Citations number
20
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron letters → ACNP
ISSN journal
00404039
Volume
35
Issue
34
Year of publication
1994
Pages
6321 - 6324
Database
ISI
SICI code
0040-4039(1994)35:34<6321:BO2A2B>2.0.ZU;2-W
Abstract
In contrast to 2-methylbenzoyloxyl radicals, 2,6-dimethylbenzoyloxyl a nd 2,4,6-trimethyl-benzoyloxyl radicals decarboxylate efficiently rath er than transfer a hydrogen atom, as observed by transient absorption spectroscopy and product distribution.