OXYFUNCTIONALIZATION REACTIONS BY PERFLUORO CIS-2,3-DIALKYTOXAZIRIDINES - ENANTIOSELECTIVE CONVERSION OF SILANES INTO SILANOLS

Authors
CAVICCHIOLI M MONTANARI V RESNATI G
Citation
M. Cavicchioli et al., OXYFUNCTIONALIZATION REACTIONS BY PERFLUORO CIS-2,3-DIALKYTOXAZIRIDINES - ENANTIOSELECTIVE CONVERSION OF SILANES INTO SILANOLS, Tetrahedron letters, 35(34), 1994, pp. 6329-6330
Citations number
10
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron letters → ACNP
ISSN journal
00404039
Volume
35
Issue
34
Year of publication
1994
Pages
6329 - 6330
Database
ISI
SICI code
0040-4039(1994)35:34<6329:ORBPC>2.0.ZU;2-2
Abstract
Perfluoro cis-2,3-dialkyloxaziridine 2 is shown to perform the oxyfunc tionalization of silanes 1 under very mild conditions to give silanols and silanediols 3 in high chemical yields and complete enantioselecti vity.