PREPARATION AND ELECTROCHEMICAL SWITCHING OF NOVEL BIS(ANTHRAQUINONE)DIAZACROWN ETHERS

Citation
L. Echegoyen et al., PREPARATION AND ELECTROCHEMICAL SWITCHING OF NOVEL BIS(ANTHRAQUINONE)DIAZACROWN ETHERS, Tetrahedron letters, 35(34), 1994, pp. 6383-6386
Citations number
15
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
ISSN journal
00404039
Volume
35
Issue
34
Year of publication
1994
Pages
6383 - 6386
Database
ISI
SICI code
0040-4039(1994)35:34<6383:PAESON>2.0.ZU;2-R
Abstract
Novel bis (anthraquinone)diazacrown ethers 1 and 2 were prepared by nu cleophilic displacement reactions on 1-fluoro-9,10-anthraquinone by di azacrown ethers. The electrochemically switched enhanced sodium bindin g capabilities of these compounds with Na+ were evaluated. Both compou nds exhibited enhanced sodium binding properties upon electrochemical reduction.