Gl. Zhang et Sj. Yu, HIGH-COERCIVITY FE NANOPARTICLES PRODUCED BY COIMPLANTATION OF FE ANDC IN CU, Journal of physics. Condensed matter, 9(8), 1997, pp. 1851-1855
A novel method was developed to prepare iron nanocrystallite by using
coimplantation of Fe and C in copper and subsequent heat treatment. Th
e formation process of iron carbide and iron granules was monitored by
means of conversion-electron Mossbauer spectroscopy, and the particle
size was determined by transmission electron microscopy. Cementite, F
e3C, was formed after annealing at 300 degrees C, then transformed to
alpha-Fe particles with a size of about 25 nm. Magnetic coercivities o
f 1.15 kOe and 0.37 kOe for the Fe granules have been observed at room
temperature (RT) and 80 K, respectively. A retained carbon-enhanced e
ffect was proposed to explain the strong coercivity at RT.