The effects of some new synthesized additives on the friction and wear
properties of a Cr2O3 coating were studied using a block-on-ring test
er under ambient conditions. The results indicate that, compared with
base oil, BMDDP, BMDOC and BMDT have friction-reducing action, BMDDP i
s effective in reducing wear but the others increase it. Test paramete
rs such as load and sliding time have a great influence on the wear pr
operties of the Cr2O3 coating but little influence on the friction pro
perties. Scanning electron microscopy and X-ray photoelectron spectros
copy analyses show that the wear-reducing action of BMDDP is a result
of the adsorption of its decomposed products and the formation of trib
ochemical reaction films on the rubbing surfaces, the wear-increasing
actions of BMDOC and BMDT mainly result from their decomposed product
H2SO4, leading to corrosive wear.