THE BEHAVIOR OF 2-METHYLENE-3-FERROCENYLMETHYLENECAMPHANE UNDER CONDITIONS LEADING TO THE CYCLODIMERIZATION OF FERROCENYL-1,3-BUTADIENES

Authors
POSTNOV VN KLIMOVA EI GARCIA MM MELESHONKOVA NN RYBAKOV VV ASLANOV LA
Citation
Vn. Postnov et al., THE BEHAVIOR OF 2-METHYLENE-3-FERROCENYLMETHYLENECAMPHANE UNDER CONDITIONS LEADING TO THE CYCLODIMERIZATION OF FERROCENYL-1,3-BUTADIENES, Journal of organometallic chemistry, 476(2), 1994, pp. 189-195
Citations number
7
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Journal of organometallic chemistry → ACNP
ISSN journal
0022328X
Volume
476
Issue
2
Year of publication
1994
Pages
189 - 195
Database
ISI
SICI code
0022-328X(1994)476:2<189:TBO2UC>2.0.ZU;2-8
Abstract
The behaviour of 2-methylene-3-ferrocenylmethylenecamphane under proto n cyclodimerization conditions has been investigated. The stage involv ing the formation of the dimeric linear allylic cation has been confir med in these interactions by isolating of corresponding diene. Its str ucture has been established unambiguously by X-ray methods. All substa nces isolated have been characterized by elemental analyses and H-1 an d C-13 NMR spectral data. .