PREPARATION AND CRYSTAL-STRUCTURE OF FAC-[MO(BPT)(CO)3] [BPT = 1,3-BIS(2-PYRIDYL)-1-THIAPROPANE]

Authors
DURRANT MC HAUSER C HUGHES DL MAGUIRE MJ RICHARDS RL
Citation
Mc. Durrant et al., PREPARATION AND CRYSTAL-STRUCTURE OF FAC-[MO(BPT)(CO)3] [BPT = 1,3-BIS(2-PYRIDYL)-1-THIAPROPANE], Journal of organometallic chemistry, 476(2), 1994, pp. 219-223
Citations number
15
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Journal of organometallic chemistry → ACNP
ISSN journal
0022328X
Volume
476
Issue
2
Year of publication
1994
Pages
219 - 223
Database
ISI
SICI code
0022-328X(1994)476:2<219:PACOF[>2.0.ZU;2-W
Abstract
The reaction of pyridine-2-thiol with 2-vinylpyridine under reflux con ditions affords a new asymmetric thioether, 1,3-bis(2-pyridyl)-1-thiap ropane (bpt), which reacts readily with [Mo(CO)3(MeCN)3] in MeCN to gi ve fac-[Mo(bptXCO)3]. The last compound has been characterised by hete ronuclear NMR spectroscopy and by an X-ray crystal structure determina tion.