1ST USE OF METHYL FORMATE WITH NO EXTRA CARBON-MONOXIDE IN THE HYDROESTERIFICATION OF ETHENE CATALYZED BY PALLADIUM COMPLEXES

Authors
GREVIN J KALCK P
Citation
J. Grevin et P. Kalck, 1ST USE OF METHYL FORMATE WITH NO EXTRA CARBON-MONOXIDE IN THE HYDROESTERIFICATION OF ETHENE CATALYZED BY PALLADIUM COMPLEXES, Journal of organometallic chemistry, 476(2), 1994, pp. 30000023-30000024
Citations number
16
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Journal of organometallic chemistry → ACNP
ISSN journal
0022328X
Volume
476
Issue
2
Year of publication
1994
Pages
30000023 - 30000024
Database
ISI
SICI code
0022-328X(1994)476:2<30000023:1UOMFW>2.0.ZU;2-R
Abstract
The complex [PdH(Cl)(PBu3)2], generated in situ by addition of one equ ivalent of NaBH4 to [PdCl2(PBu3)2], is a good catalyst precursor for t he addition of methyl formate to ethene. Extra carbon monoxide is not required, and methyl propanoate is produced with high selectivity.