CATIONIC ARENETRICARBONYLMANGANESE COMPLEXES - ADDITION OF ALPHA-ANIONIC FISCHER TYPE CARBENES

Authors
ROSEMUNCH F SUSANNE C BALSSA F ROSE E
Citation
F. Rosemunch et al., CATIONIC ARENETRICARBONYLMANGANESE COMPLEXES - ADDITION OF ALPHA-ANIONIC FISCHER TYPE CARBENES, Journal of organometallic chemistry, 476(2), 1994, pp. 30000025-30000026
Citations number
16
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Journal of organometallic chemistry → ACNP
ISSN journal
0022328X
Volume
476
Issue
2
Year of publication
1994
Pages
30000025 - 30000026
Database
ISI
SICI code
0022-328X(1994)476:2<30000025:CAC-AO>2.0.ZU;2-#
Abstract
The addition of [(CO)5M=C(OR)CH2Li] (M = Cr or W) to [(CO)3Mn(C6H6)][P F6] affords the dinuclear bridged omplexes[mu(D(OR)CH2){(eta5-C6H6)Mn( CO)3}{M(CO)5)] (3a and 3b), respectively, a similar reaction is observ ed with aminocarbene tungsten complex [(CO)5W = C(NHBut)(CH2Li)].