1,3-DIPOLAR CYCLOADDITION REACTIONS OF ALKENYLALKOXYCARBENE CHROMIUM COMPLEXES

Authors
BALDOLI C DELBUTTERO P LICANDRO E MAIORANA S PAPAGNI A ZANOTTIGEROSA A
Citation
C. Baldoli et al., 1,3-DIPOLAR CYCLOADDITION REACTIONS OF ALKENYLALKOXYCARBENE CHROMIUM COMPLEXES, Journal of organometallic chemistry, 476(2), 1994, pp. 30000027-30000029
Citations number
10
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Journal of organometallic chemistry → ACNP
ISSN journal
0022328X
Volume
476
Issue
2
Year of publication
1994
Pages
30000027 - 30000029
Database
ISI
SICI code
0022-328X(1994)476:2<30000027:1CROAC>2.0.ZU;2-M
Abstract
New spiropyrazoline derivatives from the 1,3-dipolar cycloaddition of diazomethane to alkenylalkoxycarbene complexes are isolated and fully characterized as Cr(CO)5 complexes. Me3SiCHN2 reacts selectively with the C-C double bond to give new pentacarbonylchromium carbene complexe s.