G. Mauckner et al., QUANTUM CONFINEMENT EFFECTS IN ABSORPTION AND EMISSION OF FREESTANDING POROUS SILICON, Solid state communications, 91(9), 1994, pp. 717-720
Free-standing heavily p-doped porous silicon films with varying nanocr
ystallite sizes are analysed in absorption and photoluminescence exper
iments. Blueshift of the optical absorption and of the PL-IR and S-ban
d occurs with increasing porosity, i.e. reduced nanoparticle size. Abs
orption and emission data demonstrate a continuous transition from bul
k to quantum confinement-controlled Si bandstructure.