Effect of B addition on hot workability of Fe-36%Ni alloy has been stu
died by means of hot tensile tests, micro hardness tests and physical
analyses of fractured surface. Addition of 0.002 approximately 0.004%B
was effective on improving hot workability as well as preventing slig
htly grain boundary oxidation. It was clarified by Auger Electron spec
trometer that hot workability was greatly affected by S segregation at
grain boundaries, which could be decreased by segregation of B. From
the view of diffusion of B and S, grain boundary cohesion by B segrega
tion and grain boundary oxidation, the mechanism of improvement in hot
workability of Fe-36%Ni alloys by B addition has been discussed.