P. Ketolainen et al., ON LIGHT-INDUCED SPECTRAL SHIFTS OF F(A) BANDS IN MIXED-ALKALI HALIDECRYSTALS, Journal of physics. Condensed matter, 6(34), 1994, pp. 120000517-120000520
Absorption spectra of F(A) centres were studied in Li-doped KCl-KBr an
d KCl-RbCl mixed crystals. In KCl-KBr, light-induced spectral shifts w
ere observed at liquid nitrogen temperature, for the F(A1) band toward
s lower energy and for the F(A2) band towards higher energy. The shift
s are thought to be due to structural change where the electron-occupi
ed vacancy finds a new location in relation to the neighbouring chlori
ne and bromine ions.