Pj. Sebastian et al., THE STRUCTURAL, TRANSPORT AND OPTICAL-PROPERTIES OF SCREEN-PRINTED CUXS THICK-FILMS, Solar energy materials and solar cells, 32(2), 1994, pp. 159-168
The structural, transport and optical properties of screen printed Cu(
x)S thick films with possible application in photovoltaic and photothe
rmal devices are reported. The X-ray diffraction studies show that the
screen printed films are stable up to about 220-degrees-C in air and
belong to the Cu(x)S structure. Above this temperature it decomposes m
ainly to CuSO4. The electrical conductivity depends on the sintering t
emperature and the amount of flux, Cu(NO3)2, used in the paste for scr
een printing. The differential scanning calorimetry studies reveal the
phase changes occurring during heating and pertaining to the dependen
ce of electrical conductivity on the sintering temperature. A configur
ation consisting of screen printed Cu(x)S on chemically deposited and
annealed (at 200-degrees-C) CdS thin film exhibited rectification.