A CONVENIENT SYNTHESIS OF 2-THIO-SUGARS AND SYMMETRICAL BETA-KETO-SULFIDES FROM 2,3-DIDEOXY-HEX-2-ENOPYRANOSE-4-ULOSES

Authors
APOSTOLOPOULOS CD COULADOUROS EA GEORGIADIS MP
Citation
Cd. Apostolopoulos et al., A CONVENIENT SYNTHESIS OF 2-THIO-SUGARS AND SYMMETRICAL BETA-KETO-SULFIDES FROM 2,3-DIDEOXY-HEX-2-ENOPYRANOSE-4-ULOSES, Polish Journal of Chemistry, 68(9), 1994, pp. 1725-1729
Citations number
11
Categorie Soggetti
Chemistry
Journal title
Polish Journal of Chemistry → ACNP
ISSN journal
01375083
Volume
68
Issue
9
Year of publication
1994
Pages
1725 - 1729
Database
ISI
SICI code
0137-5083(1994)68:9<1725:ACSO2A>2.0.ZU;2-L
Abstract
Michael addition of thiols or inorganic sulfur anions to several 5-sub stituted 2,3-dideoxy-hex-2-enopyranose-4-uloses 1-4, afforded stereose lectively 2-thio-sugars 5-11, or beta-keto-sulfides 12a and 12b, respe ctively.