STABLE AND UNSTABLE PRODUCTS ON THE REACT ION OF 2,2-DIPHENYL-1,2-DIHYDROQUINOLINENITROXIDE RADICALS WITH NITRIC-OXIDE

Authors
WEBER H GRZESIOK A SUSTMANN R KORTH HG
Citation
H. Weber et al., STABLE AND UNSTABLE PRODUCTS ON THE REACT ION OF 2,2-DIPHENYL-1,2-DIHYDROQUINOLINENITROXIDE RADICALS WITH NITRIC-OXIDE, Zeitschrift fur Naturforschung. B, A journal of chemical sciences, 49(8), 1994, pp. 1041-1050
Citations number
17
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Zeitschrift fur Naturforschung. B, A journal of chemical sciences → ACNP
ISSN journal
09320776
Volume
49
Issue
8
Year of publication
1994
Pages
1041 - 1050
Database
ISI
SICI code
0932-0776(1994)49:8<1041:SAUPOT>2.0.ZU;2-G
Abstract
The stable 2,2-diphenyl-1,2-dihydroquinolinenitroxide radicals 1 react with nitric oxide (NO) to form the stable nitro compounds 2 and 3 as main products. The stable dinitro compounds 6 and 1,2-dihydroquinoline s 7 are formed in minor yield as side-products accompanied with the un stable N-nitroso compounds 4 and 5, which further decompose to form th e stable products mentioned above. The proposed mechanism of the react ion is discussed in terms of homolytical processes and is supported by PM3 calculations.