Mg. Siemann, AMMONIUM BEARING CARNALLITE [(K NH4)MGCL3-CENTER-DOT-6H2O] IN THE SALT MINE MARIE (MORSLEBEN)/, Neues Jahrbuch fur Mineralogie Monatshefte, (3), 1994, pp. 97-100
Carnallites with a not yet known content of NH4 were found as ground c
rystals in solution pools at the locality ''Bunte First'' of the salt
mine ''Marie'', ERA Morsleben. These carnallites contain 0.2 to 0.8 %
NH4. The NH4 is inserted in the carnallite structure instead of K. The
partition coefficient b of NH4 in carnallite is about 10. Additionall
y a new phase with 2.06 % NH4 Was found. The composition of this new p
hase is [K2(NH4)Mg3Cl9 . 18 H2O].