Mr. Bermejo et al., INTERHALODERIVATIVES OF THALLIUM(III) COMPLEXES WITH 1-METHYL-2-PHENYLIMIDAZOLE, Synthesis and reactivity in inorganic and metal-organic chemistry, 24(8), 1994, pp. 1397-1410
The following compounds: TlBrCl2.2L, TlICl2.3L, TlBr2Cl.2L, TlIBr2.2L,
TlI2Cl.2L, TlI2Br.2L, TlI2Br.3L, and TlIBrCl.2L (where L = 1-methyl-2
-phenylimidazole) have been prepared and characterized by elemental an
alyses. All the solids are monomers and they behave as non-electrolyte
s in solution. Their H-1 NMR and IR spectra are discussed, especially
the Tl-X stretching vibration modes, and possible molecular structures
for the complexes are proposed.