INTERHALODERIVATIVES OF THALLIUM(III) COMPLEXES WITH 1-METHYL-2-PHENYLIMIDAZOLE

Citation
Mr. Bermejo et al., INTERHALODERIVATIVES OF THALLIUM(III) COMPLEXES WITH 1-METHYL-2-PHENYLIMIDAZOLE, Synthesis and reactivity in inorganic and metal-organic chemistry, 24(8), 1994, pp. 1397-1410
Citations number
7
Categorie Soggetti
Chemistry Inorganic & Nuclear
ISSN journal
00945714
Volume
24
Issue
8
Year of publication
1994
Pages
1397 - 1410
Database
ISI
SICI code
0094-5714(1994)24:8<1397:IOTCW1>2.0.ZU;2-F
Abstract
The following compounds: TlBrCl2.2L, TlICl2.3L, TlBr2Cl.2L, TlIBr2.2L, TlI2Cl.2L, TlI2Br.2L, TlI2Br.3L, and TlIBrCl.2L (where L = 1-methyl-2 -phenylimidazole) have been prepared and characterized by elemental an alyses. All the solids are monomers and they behave as non-electrolyte s in solution. Their H-1 NMR and IR spectra are discussed, especially the Tl-X stretching vibration modes, and possible molecular structures for the complexes are proposed.