By simultaneously measuring the phonon scattering at or near a silicon
surface and the phonon transmission from it into liquid helium, we ha
ve correlated quantitatively these two processes. For a clean polished
silicon surface, the scattering of thermal phonons below 0.3 K become
s very small, and the transmission probability in this case approaches
the prediction of the acoustic mismatch theory, which is 0.27%. The t
ransmission probability increases, i.e. the thermal boundary resistanc
e decreases, as the diffuse scattering increases either as a result of
increasing the phonon frequency or the disorder at the surface. In th
e limit of completely diffuse scattering, the phonon transmission prob
ability exceeds 30%, and the thermal boundary resistance approaches th
e value predicted by the diffuse mismatch model to within a factor of
three.