R. Aravind et al., VAPOR-GROWN CARBON-FIBERS - MODELING OF FILAMENT LENGTH DISTRIBUTIONS, Journal of analytical and applied pyrolysis, 28(2), 1994, pp. 255-270
A mechanistic model has been used to predict filament length distribut
ions for vapor grown carbon fibers during the lengthening stage. Optim
al values for the two parameters, alpha and Lt, in this model are obta
ined by curve-fitting one set of experimental results, giving excellen
t agreement. The model can easily be used to predict length distributi
ons for cases where alpha and L vary with time in any prescribed manne
r. Results are obtained for the case where alpha undergoes a step incr
ease after some time, and it is found that the filament length distrib
utions are quite sensitive to the history, alpha(t). In fact, situatio
ns can easily be found for which the mean lengths are identical, but t
he distributions differ significantly.