LIQUID-LIQUID SOLID REACTIONS - ESTERIFICATION OF PHENOL WITH BENZOYLCHLORIDE USING A POLYMER-SUPPORTED PHASE-TRANSFER CATALYST

Authors
DUTTA NN PANGARKAR VG
Citation
Nn. Dutta et Vg. Pangarkar, LIQUID-LIQUID SOLID REACTIONS - ESTERIFICATION OF PHENOL WITH BENZOYLCHLORIDE USING A POLYMER-SUPPORTED PHASE-TRANSFER CATALYST, Reactive polymers, 22(1), 1994, pp. 9-17
Citations number
12
Categorie Soggetti
Polymer Sciences","Engineering, Chemical","Chemistry Applied
Journal title
Reactive polymers → ACNP
ISSN journal
09231137
Volume
22
Issue
1
Year of publication
1994
Pages
9 - 17
Database
ISI
SICI code
0923-1137(1994)22:1<9:LSR-EO>2.0.ZU;2-L
Abstract
The reaction of phenol in alkaline solution and benzoyl chloride disso lved in toluene with a polymer-supported tri-n-butylphosphonium ion as phase transfer catalyst has been carried out in a slurry reactor. Mas s transfer effects have been analysed with the standard theory of poro us catalysts. The intrinsic reaction rate constant and diffusion coeff icients within the porous polymer particle are estimated. The rate-lim iting step has been identified.